Download Full PDF
Read Complete Article
~ 649
` 1116
a 18-27
Volume 2 - May 2013
Abstract
The focus of this paper is to examine and review how applications of Electrochemical Chloride Extraction (ECE) affect the mortar mechanical properties. The mortar specimens were prepared with water/cement (w/c) ratio of 0.5 and contaminated with 5% of NaCl by mass of cement. A clean steel rod was centrally embedded in each specimen. The electrochemical treatments were based on different electrical current densities of 1, 3, 6 and 9 A/m2 that were applied for 15 days. The state of corrosion was monitored before, during and after applying ECE regularly for two weeks. Selected samples from the cover zone of the untreated and treated specimens were taken to assess their chloride profiles. Despite being a slight change in the microstructure at the surface of the steel rod when this technique was applied (high current densities), the results of the compressive strength on mortars were not affected by ECE.
Keywords
Corrosion, Chloride, Mortar, Microstructure, Compressive Strength
References
- P. Claude Aı̈tcin, Cements of yesterday and today: Concrete of tomorrow. Cem. Concr. Res.30, 2000 (9) 1349–1359
- K. Yong Ann, H. Won Song, Chloride threshold level for corrosion of steel in concrete. Corros. Sci. 49, 2007 (11) 4113–4133
- J. Gulikers, Development of a galvanic monitoring probe to improve service life prediction of reinforced concrete structures with respect to reinforcement corrosion. Constr. Build. Mater. 11, 1997 (3) 143–148
- V. Saraswathy H. Won Song, Electrochemical studies on the corrosion performance of steel embedded in activated fly ash blended concrete. Electrochim. Acta 51, 2006 (22), 4601–4611
- G.S. Duffó, S.B. Farina C.M. Giordano, Characterization of solid embeddable reference electrodes for corrosion monitoring in reinforced concrete structures. Electrochim. Acta, 2009, 54 (3) 1010-1020
- A. Muntean, M. Böhm, J. Kropp, Chemical Engineering Science, 2011, 66 (3) 538–547
- M. Grantham, Diagnosis, inspection, testing and repair of reinforced concrete structures. Advanced Concrete Technology Set, 2003 Volume 2, 1-54
- M. Miranda, E. Otero, J.A. González, Limitations and advantages of electrochemical chloride removal in corroded reinforced concrete structures. Cem. Concr. Res. 37, 2007 (4) 596–603
- G. Fajardo, G. Escadeillas, G. Arliguie, Electrochemical chloride extraction (ECE) from steel-reinforced concrete specimens contaminated by “artificial†sea-water. Corros. Sci. 48, 2006 (1) 110-125
- J.C Orellan, G Escadeillas, G Arliguie, Electrochemical chloride extraction: efficiency and side effects . Cem. Concr. Res. 34, 2004 (2) 227-234
- P. Garcés, M.J. Sánchez de Rojas, M.A. Climent, Effect of the reinforcement bar arrangement on the efficiency of electrochemical chloride removal technique applied to reinforced concrete structures. Corros. Sci. 48, 2006 (3) 531-545
- Nzeribe M. Ihekwaba, Brian B. Hope, Mechanical properties of anodic and cathodic regions of ECE treated concrete. Cem. Concr. Res. 26, 1996 (5) 771-780
- ASTM C192/C192M-07. Standard practice for making and curing concrete test specimens in the laboratory, Book of standards, 2007 Vol. 04.02
- ASTM C39/C39M-05e1. Standard test method for compressive strength of cylindrical concrete specimens book of standards,2005 vol. 04.02
- M. Stern, A.L. Geary, J. Electrochemical Soc. 1957, 104 (56)
- ASTM C-876-91. Standard test method for half-cell potentials of uncoated reinforcing steel in concrete; 1999
- MF. Asaro, AT. Gaynor, S.Hettiarachi, Electrochemical chloride removal and protection of concrete bridge components Strategic highway research program report SHRP–S/FR-90– 002. Washington (DC): NRC; 1990
- M. Sánchez , M.C. Alonso, Electrochemical chloride removal in reinforced concrete structures: Improvement of effectiveness by simultaneous migration of calcium nitrite . Construction and Building Materials, 2011, 25 (2) 873–878
- G.E. Abdelaziz , A.M.K. Abdelalim, Y.A. Fawzy, Evaluation of the short and long-term efficiencies of electro-chemical chloride extraction Cem. Concr. Res. 2009, 39 (8) 727–732
- C. Andrade, I. Martinez, Castellote, “Efficiency control electrochemical repair techniquesâ€. Concrete repair, Rehabilitation and Retrofitting II, South Africa, 2008, p. 24-26
- B. Elsener, U. Angst, Mechanism of electrochemical chloride removal . Corros. Sci. 2007, 49 (12) 4504-4522
- W.K. Green, S.B. Lyon, J.D. Scantlebury, Electrochemical changes in chloride-contaminated reinforced concrete following cathodic polarisation. Corros. Sci. 1993, 35 (5) 1627–1631
- N.R. Buenfeld J.P. Broomfield, International Conference on Corrosion Protection of steel in Concrete, Sheffield, UK, (1994) 1438-1451
- N.M. Ihekwaba, B.B. Hope, C.M. Hansson, Pull-out and bond degradation of steel rebars in ECE concrete. Cem. Concr. Res. 1996, 26 ( 2) 267-282
- J.B. Miller, Structural aspects on high powered electrochemical treatment of reinforced concrete, in: Proccedings of the International Conference on Corrosion and Protection of Steel in Concrete, 24-28 July, Sheffield, UK, 1994
- T.D. Marcotte, C.M. Hansson, B.B. Hope, The effect of the electrochemical chloride extraction treatment on steel-reinforced mortar Part I: Electrochemical measurements . Cem. Concr. Res. 1999, 29 (10) 1555-1560
- M. Siegwart, F. Lyness, J. McFarland, Change of pore size in concrete due to electrochemical chloride extraction and possible implications for the migration of ions. Cem. Concr. Res. 2003, 33 (8) 1211-1221
- Kalliopi K Aligizaki, Mario R de Rooij, Digby D Macdonald. Analysis of iron oxides accumulating at the interface between aggregates and cement paste. Cem. Concr. Res. 2000, 30 (12) 1941-1945
- S. Rodriguez, J. Miranda , C. Gaona, L. Narváez, L. Hernández, Port. Electrochim. Acta 2010, 28 (3) 153-164. Estado de la Corrosión en Probetas de Acero Embebidas en Mortero después de una Extracción ElectroquÃmica de Cloruros.. ISSN 0872-1904
Cite this Article:
International Journal of Sciences is Open Access Journal.
This article is licensed under a Creative Commons Attribution 4.0 International (CC BY 4.0) License.
Author(s) retain the copyrights of this article, though, publication rights are with Alkhaer Publications.