A Novel Method for Synthesis of CoII, NiII, ZnII and AgI Transition Metal Carbonates using Methylurea Precursor

A Novel Method for Synthesis of CoII, NiII, ZnII and AgI Transition Metal Carbonates using Methylurea Precursor

Loading document ...
Page
of
Loading page ...

Author(s)

Author(s): Moh`d Mamoun Al Majthoub

Download Full PDF Read Complete Article

469 934 119-123 Volume 2 - Sep 2013

Abstract

CoII, NiII, ZnII and AgII carbonates; M(CO3)2 (M = CoII, NiII, and ZnII) and Ag2CO3 were obtained during the reaction of aqueous solutions of Co(NO3)2, Ni(NO3)2, Zn(NO3)2 and AgNO3 with methylurea at ~ 90 oC for twelve hours. The reaction products were characterized through their elemental analysis and infrared spectroscopy. The infrared spectra clearly show the characteristic bands due to carbonate ions. General reaction equations describing the formation of some transition carbonates were proposed.

Keywords

M(CO3)2, methylurea, Infrared spectra

References

  1. A. Seminara, A. Musumeci, A. Chisari, Uranyl and lanthanide complexes with ureas. Synthesis and spectroscopic studies, J. Inorg. Nucl. Chem., 40(2), 269 (1978)
  2. G. Siracusa, A. Seminara, V. Cucinotta, S. Gurrieri, Thermal decomposition of metal complexes. VII. Uranyl nitrate-urea system: synthesis and decomposition, Thermochim. Acta, 23(1), 109 (1978)
  3. P.S. Gentile, L.H. Talley, Coordination compounds of uranium with organic bases in aqueous solution, J. Amer. Chem. Soc., 79, 5889 (1957)
  4. Yu. Ya. Kharitonov, K.S. Sulaimankulov, N.B. Khudaibergenova, IR absorption spectra of rare earth nitrate complexes with urea, Zh. Neorg. Khim., 35 (8), 2117 (1990)
  5. C.V. Deshpande, V.R. Rao, Preparation and characterization of lanthanide complexes using substituted ureas and thioureas as ligands, J. Indian Inst. Sci., 69(5), 329 (1989)
  6. P. V. Vaidya, V. D. Deshpande, R. Rao, Synthesis and characterization of lanthanide mixed complexes using urea and phenylthioureas as ligands, J. Indian Council of Chemists, 3(1), 21 (1987)
  7. M. A. Tushchenko, V. B. Rybalka, A. I. Markina, A. A. Kostyuk, A. S. Tsitko, E. T. Denisenko, Complexation of rare earth ions with urea in solution, Organ. Reagenty Anal. Khimii, Perm. Gos. Un-t, Perm (1991), 43-38. From: Ref. Zh., Khim. 1992, Chem. Abstr. No. 121:93018
  8. M.K. Balbaev, I.K. Kireeva, K.S. Sulaimankulov, A. Yu. Tsivadze, Koord. Khim., Urea compounds of double rare earth sulfates, Koord. Khim. 14(2), 186 (1988)
  9. B. Murzubraimov, M. Ismailov, Thermal stability of some rare earth metal acetate complexes with urea, Zh. Neorg. Khim., 30(1), 70 (1985)
  10. B. Murzubraimov, Coordination compounds of d- and f-metals with amide ligands, Koord. Khim., 11(12), 1587 (1985)
  11. S. M. Teleb, M. S. Refat , S. A. Sadeek, Spectroscopic studies of the reaction products of urea with Sn(IV) and Sn(II) chlorides at room and high temperature, Ukrainian Chem. J., 68(5), 35 (2004)
  12. S. A. Sadeek, M. S. Refat , S. M. Teleb, Spectroscopic and thermal studies of [Cr2(NH2)2(H2O)2 (SO4)2].2H2O, [Cr(NCO)3(H2O)].3H2O and [FeO(OH)].0.5H2O compounds formed by the reactions of urea with Cr2(SO4)3, Cr(CH3COO)3 and Fe2(SO4)3, J. Korea, Chem. Soc., 48(4), 358 (2004)
  13. M. S. Refat, S. M. Teleb, S. A. Sadeek, A novel method for preparation of cobalt(II) and lead(II) carbonates, Spectrochim. Acta, A(60), 2803 (2004)
  14. M. S. Refat, S. A. Sadeek, S. M. Teleb, Reactions of urea with Mo(VI), V(V) and Se(IV) oxides at high temperature, J. Argen. Chem. Soc., 92(4-6), 23 (2004)
  15. M. S. Refat, A novel method for the synthesis of rare earth carbonates, Synth. React. Inorg. Met.-Org. Chem., 34(9), 1605-1613 (2004)
  16. E. M. Nour, S.M. Teleb, N.A. Al-Khososy, M. S. Refat, A novel method for the synthesis of metal carbonates. I. synthesis and infrared spectrum of manganese carbonate, MnCO3.H2O, formed by the reaction of urea with manganese(II) salts, Synth. React. Inorg. Met-Org. Chem., 27(4), 505 (1997)
  17. K. Nakamoto, "Infrared and Raman Spectra of Inorganic and Coordination Compounds", Wiley, New York, 1978

Cite this Article:

  • BibTex
  • RIS
  • APA
  • Harvard
  • IEEE
  • MLA
  • Vancouver
  • Chicago

International Journal of Sciences is Open Access Journal.
This article is licensed under a Creative Commons Attribution 4.0 International (CC BY 4.0) License.
Author(s) retain the copyrights of this article, though, publication rights are with Alkhaer Publications.

Search Articles

Issue October 2019

Volume 8, October 2019


Table of Contents


Order Print Copy

World-wide Delivery is FREE

Share this Issue with Friends:


Submit your Paper